1. A mountain biker goes for a ride in the desert. The air temperature is 21°C at the start of the ride, but the temperature in the desert will reach a peak of 51°C. The tires on the bike hold 15.6 L of nitrogen gas at a starting pressure of 249 kPa. The tires will burst when the internal pressure (Pb) reaches 269 kPa. Answer the following questions and show your work. • How many moles of nitrogen gas are in each tire? • What will the tire pressure be at the peak temperature in the desert? • Will the tires burst at the peak temperature? Explain. • To what pressure should the tire pressure be reduced before starting the ride to avoid bursting of the tires in the desert heat? (Assume no significant change in tire volume.)